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本文中采用脉冲激光沉积的方法原位制备了结构完整的La1.89Ce0.11CuO4(LCCO)/Ba0.7Sr0.3TiO3(BST)/La0.67Sr0.33MnO3(LSMO)三层膜,并在此基础上制得了类似P-I-N型的全钙钛矿结构材料异质结.在不同的温度区间对其电输运性质进行了测量.测量结果表明随着充当绝缘层的Ba0.7Sr0.3TiO3的厚度的变化,异质结的电输运机制也在变化.当其厚度到达25纳米时,整个结在低温区呈现良好的整流特性. 相似文献
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STUDY ON PREPARATION OF UV CROSS-LINKING FILMS OF POLYURETHANE-LiClO4 COMPLEXES AND THEIR IONIC CONDUCTIVITY 下载免费PDF全文
The complexes of polyurethane containing double bonds with LiClO4 were formed, and cross-linked films were produced by UV radiation, All of the films were uniform, transparent, flexible and smooth-faced with a considerable mechanical strength. The ionic conductivities of the films of several series of polymers with different molecule weights of PEG segment were measured, of which the highest is 8.09×10-5S·cm-1 at 300K under anhydrous atmosphere. Also the conductivity is deeply influenced by the molecule weight of the soft segment PEG of the polyurethane and the content of LiClO4. The transport number of Li+ is about 0.57. Structure characteristic measurement much as DSC, XRD, IR etc., have been done and the conductive mechanism is discussed. 相似文献
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STUDIES OF ELECTRON SPIN RESONANCE ON BILIRUBIN FREE RADICALS 总被引:1,自引:0,他引:1
The nature of ESR signals derived from bilirubin-Ⅸα has been studied by focusing onthe samples treated with free radical generating and inhibiting systems, i.e. X-XOD, Fe/EDTA, SOD, mannitol/ascorbate, CO, KCN, etc. In all the cases, the stable signals comprisethose originated from semiquinone radical (g = 2.0012) and superoxide free radical (g_∥=2.041, g_⊥= 2.0040). The superoxide is shown binding with certain metal ions chelated bybilirubin. The free radical scavengers are able to destroy these radicals. The kinetic curveof the regeneration of bilirubin radicals has been determined and the reaction follows azero order mechanism. It is likely that both the physiological and toxic actions of bilirubinare related to the characters of its free radicals. Bilirubin is discussed as "active oxygensink" in mammalians. 相似文献
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等电位辉光放电电子温度的光谱测量与计算 总被引:3,自引:0,他引:3
用SII- IV 型全息凹面光栅单色仪对各种工艺参数条件下双层辉光等电位放电的发射光谱的相对强度进行了测量, 获得一系列光谱谱线。通过对玻尔兹曼方程式的计算, 得到了不同工艺条件下等离子放电时的电子温度。分析了工件电压、工作气压对电子温度的影响。结果表明: 在本工艺条件下, 电子温度随着工件电压的升高, 先减小后增大, 然后又减小, 并随着工作气压的增大而单调增大。工作气压的变化较工件电压的变化对电子温度的影响大。 相似文献
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研究了由非磁性聚苯乙烯颗粒弥散于煤油基Fe_3O_4磁性液体中制备而成的磁性液体复合体.该复合体双折射效应和线二向色性随外磁场变化.在相同的磁场条件下,复合体的双折射效应较纯磁性液体有减弱而二向色性较后者有所增强.文中采用一简化模型对结果给出了解释. 相似文献
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